四川紫色雏形土的蒸发性及其与土壤结构性的关系     

宫阿都  何毓蓉 《山地学报》2001,(Z1)

结合四川土壤基层分类 ,选取四川紫色雏形土的几个土系 ,对土壤的水分发性能及其与土壤结构性尤其是机械组成和微团聚体组成的相关关系分析发展 ,土壤水分蒸发具有明显的阶段性 ;土壤水分累积蒸发量与蒸发历时之间总体上符合乘幂方程 ;土壤蒸发速度与〈0 .0 0 1mm的颗粒含量呈明显相关关系 ,与 >0 .2 5mm的大团聚体含量呈明显负相关关系。  相似文献   

含粘粒砂土抗液化性能的试验研究   总被引：20，自引：1，他引：20  

衡朝阳  何满潮  裘以惠 《工程地质学报》2001,9(4):339-344

通过对含粘粒砂土所作的试验研究, 包括: 粘粒矿物成分不同、粘粒含量不同的重塑土样所作的室内动三轴试验; X光衍射试验, 试验结果对比分析后, 得出了含粘粒砂土抗液化性能的特性。并得出以下结论: (1)粘粒矿物成分不同, 也引起砂土动力稳定性的变化; (2 )动剪应力强度与粘粒含量并非呈单调增加关系, 而呈抛物线型, 并给出回归方程; (3)含粘粒的砂土, 其抗液化能力最低点总是在粘粒含量 8.5～ 9.5 %之间。  相似文献   

pH influence on sorption characteristics of heavy metal in the vadose zone   总被引：10，自引：0，他引：10  

M. Elzahabi  R. N. Yong 《Engineering Geology》2001,60(1-4):61-68

Sorption is an important process in the modelling and prediction of the movement of heavy metals in unsaturated clay barriers. This experimental study investigates the effect of pH changes in the acidic range on the sorption characteristics of heavy metals such as: lead, copper and zinc in an unsaturated soil. A series of one-dimensional coupled solute and moisture leaching column tests, using different heavy metal solutions, were conducted on an unsaturated illitic soil at varying pH values. Variations of volumetric water content (VWC) with distance were measured for different time durations, and concentrations of heavy metals in the liquid and solid phases were analysed. Partitioning coefficient profiles of contaminants along the soil column were determined for each individual layer in the soil.

Results from column leaching tests showed that the sorption characteristics of heavy metals are controlled by many factors which should be taken into consideration, i.e. the VWC, time of wetting, soil pH, and the influent heavy metal concentrations. Simplification of K_d as a constant and of the VWC as a linear function cannot be considered a good assumption and may lead to an improper evaluation of the sorption phenomena and also to serious errors in predicting contaminant transport through unsaturated soils.  相似文献   

一次三峡大暴雨的地转螺旋度分析   总被引：5，自引：4，他引：5  

吴宝俊  于永安 《气象科学》1996,16(2):142-150

本文引入了地转螺旋度概念，并将其用于一次大暴雨的分析，结果发现；在地转螺旋度垂直剖面图上，在雨区上空３００ｈＰａ附近有一个负的极小值中心，在５００ｈＰａ有一个正的极大值中心，该分布形成原因可用图６解释。  相似文献   

Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds   总被引：15，自引：0，他引：15  

Pradeep Saxena  Lynn M. Hildemann 《Journal of Atmospheric Chemistry》1996,24(1):57-109

Although organic compounds typically constitute a substantial fraction of the fine particulate matter (PM) in the atmosphere, their molecular composition remains poorly characterized. This is largely because atmospheric particles contain a myriad of diverse organic compounds, not all of which extract in a single solvent or elute through a gas chromatograph; therefore, a substantial portion typically remains unanalyzed. Most often the chemical analysis is performed on a fraction that extracts in organic solvents such as benzene, ether or hexane; consequently, information on the molecular composition of the water-soluble fraction is particularly sparse and incomplete.This paper investigates theoretically the characteristics of the water-soluble fraction by splicing together various strands of information from the literature. We identify specific compounds that are likely to contribute to the water-soluble fraction by juxtaposing observations regarding the extraction characteristics and the molecular composition of atmospheric particulate organics with compound-specific solubility and condensibility for a wide variety of organics. The results show that water-soluble organics, which constitute a substantial fraction of the total organic mass, include C2 to C7 multifunctional compounds (e.g., diacids, polyols, amino acids). The importance of diacids is already recognized; our results provide an impetus for new experiments to establish the atmospheric concentrations and sources of polyols, amino acids and other oxygenated multifunctional compounds.  相似文献   

株州市土壤重金属污染的对应分析   总被引：3，自引：0，他引：3  

尚金城  龙爱民 《地理科学》1996,16(1):73-78

株州市土壤重金属污染的主要原因是工厂排放有害气体，或是水体污染物随灌溉进入土壤。采用对应分析方法，将市区土壤重金属污染分析３种类型。靠近人业污染源附近，镉的含量及污染指数高；大部分土壤受多种重金属污染；水稻土主要表现为铅的污染。  相似文献   

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren     

M. Sager  W. Vogel 《洁净——土壤、空气、水》1993,21(1):21-32

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.  相似文献   

Effects of Deicing-Salts on Heavy Metal Mobility Zum Einfluß von Streusalzen auf die Beweglichkeit von Schwermetallen     

B. Bauske  D. Goetz 《洁净——土壤、空气、水》1993,21(1):38-42

Heavy metal input into roadside soils and effects of deicing salts are often discussed as separate environmental problems. However, a relationship between salt input and heavy metal mobility has already been detected in laboratory tests. During a 2-year field study, the soil solution of a roadside soil was continuously sampled. The results of soil solution analysis not only showed a strong rise in deicing-salt related sodium, calcium and chloride concentrations, but also high zinc and cadmium values in winter and spring. Additional laboratory tests confirmed the mobilizing effects of salt solution which contained NaCl and CaCl₂. Cation exchange and the formation of chlorocomplexes are discussed as the responsible mechanisms.  相似文献   

Use of Factor Analysis to Study the Distribution of Metalliferous Bauxitic Tailings in the Seabed of the Gulf of Corinth,Greece     

Papatheodorou  G.  Lyberis  E.  Ferentinos  G. 《Natural Resources Research》1999,8(4):277-286

In 1994, a detailed marine environmental survey was carried out in surface sediments of the northern flank (Antikyra Bay) and the basin floor of the Gulf of Corinth. Metalliferous tailings (red-mud slurry) of a bauxite processing plant are discharged through a pipeline at a water depth of 100 m, in the Antikyra Bay, covering an area of 16 km². The bauxitic tailings are detached from the main deposit at the outfalls, flow as turbidity currents downslope, and are redeposited on the basin floor of the Gulf of Corinth, where they cover an area of about 277 km². One hundred sediment samples, that were collected from red-mud deposits and the surrounding natural sediments, were analyzed for Ag, Al, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Si, Ti, V, and Zn concentrations. Statistical analysis of the heavy metals concentrations using factor analysis allowed (i) an examination of the interrelations among metals and (ii) distinguishing possible sample groups on the basis of metal concentrations in order to study the mechanisms of transport of the red mud and the degree of mixing with natural sediments. Factor 1 (Al, Cr, Ti, Fe, Co, Ni, Pb, Ag, Hg, V, Cd, and Cu) and the positive pole of Factor 2 (Cu, Ag, Cd, and Hg) are red-mud factors, reflecting different metal behaviors, which are related to processes that take place during the transport and redeposition of the red mud. The negative poles of Factors 2 and 3 and the positive pole of Factor 4 are related to natural sediment supply processes. Q-mode factor analysis identifies three distinct sediment groups located in different areas, on the base of the degree of mixing of red mud with natural sediments.  相似文献   

一次东北冷涡过程的宏微观物理特征分析     

李冬楠  刘星光  高倩楠  袁潮  李鹏  安英玉 《气象科技》2021,49(2):227-234

利用2019年5月20日机载DMT和SPEC粒子测量系统获取的飞机云微物理探测资料,结合高空、地面、卫星云图产品等常规气象数据,分析了东北冷涡在发展成熟期的云宏微观结构特征。结果表明:飞机探测区域为冷性层积混合云,云水充沛。云粒子探头(CDP)和二维云粒子图像探头(CIP)探测到的最大粒子数浓度分别为362.10cm~(-3)、191.08L~(-1),液态含水量变化范围为0～0.88g/m~3;CDP粒子谱呈指数型下降,谱宽较窄;CIP粒子谱呈双峰结构。云粒子图像探测仪CPI表明,层积云上部主要为冰雪晶粒子,以冰晶的核化和凝华增长为主;中上部粒子主要为小冰晶形态,也有冰晶聚合体和枝状冰晶;中下部是过冷水和冰晶粒子的共存区,过冷水较为丰富。  相似文献